The celebrated Seq2Seq technique and its numerous variants achieve excellent performance on many tasks such as neural machine translation, semantic parsing, and math word problem solving. However, these models either only consider input objects as sequences while ignoring the important structural information for encoding, or they simply treat output objects as sequence outputs instead of structural objects for decoding. In this paper, we present a novel Graph-to-Tree Neural Networks, namely Graph2Tree consisting of a graph encoder and a hierarchical tree decoder, that encodes an augmented graph-structured input and decodes a tree-structured output. In particular, we investigated our model for solving two problems, neural semantic parsing and math word problem. Our extensive experiments demonstrate that our Graph2Tree model outperforms or matches the performance of other state-of-the-art models on these tasks.